Sorry for digging up this old thread. Killing a little time on a Sunday morning before heading out to the garage to prep the car for next season and found this old oil related thread.
Quiky One said:
All new oils sold in stores (5w-30 and 10w-30) have to adhere to the AN spec for street cars which is 800PPM zinc and 800PPM Phosphorus.
The API SN specification limit is only on phosphorus (at 800 ppm). There is no limit on zinc. However, for the anti-wear additive ZDDP, or zinc dialkyl dithio phosphate, as the zinc bonds with phosphorus, there is an effective limit on zinc at about 900 ppm.
Quiky One said:
Racing oils and break in oils are only good for 500 miles.
If that is all you drive, go for it. Otherwise, it will break down (viscosity and the other additives) too fast.
While I agree that 500 miles is about right for a racing or break-in oil, I wouldn't characterize the reason as "break down". The main difference between a racing/break-in oil and a street oil in terms of longevity is the detergent/dispersant, primarily calcium. The detergent/dispersant allows an oil to resist acidic engine combustion by-products that get by the rings and into the oil. As the oil is used, it gets more and more acidic. Long life oils have lots of detergent/dispersant. "Normal" street oils have some detergent/dispersant. Racing/Break-in oils generally have little to none.
This can be seen in the oil's Total Base Number (opposite of acidic) which some oil companies report. Higher TBN is more basic, low TBN is more acidic. Scale is to 14. The higher the TBN the longer the oil can resist acidic buildup. Most oil analysis labs will state that running the oil until the TBN is 1.0 is okay, though in my opinion that is pretty acidic. Here are some examples from AMSOIL (all full synthetic):
- Signature Series 5w30: 12.6
(this is a 25k mile/one year oil, 15k in severe service)
- XL 5w30: 9.0
(10k mile/six month or per OEM)
- OE 5w30: 7.9
(OEM oil change interval)
- Break-In SAE 30: 6.6
(not to exceed 1000 miles)
On the topic of anti-wear additives in general for the OP:
From 94-97, the API SH spec allowed up to 1200 ppm phosphorus for 5w30 and 10w30 and didn't address other 30 grade viscosity like 0w30. In 97, API SJ dropped the limit to 1000 ppm, but still did not address 0w30. In 01, API SL kept 1000 ppm phosphorus, but added 0w30 to the spec. In 04, API SM further dropped the limit to 800 ppm, but for the first time set a floor at 600 ppm and advertised that oil's were better. Essentially they were capping how much phosphorus the better oils could have and mandating the lowest amount the cheapest oils must have. The current API SN spec still has the band 600-800 ppm phosphorus.
Unfortunately, phosphorus, along with zinc, in a compound called ZDDP, or or zinc dialkyl dithio phosphate, forms an oil's primary anti-wear additive. The reason behind this is that phosphorus slowly poisons the cats and prevent the catalytic exchange that allows them to function properly. To ensure auto companies could meet the EPA's 100k+ emissions requirements, the API has slowly been dropping the limit on phosphorus.
So, any oil labeled to meet the current API SN spec will be limited to 800 ppm max phosphorus. This impacts how well it will be able to perform in anti-wear, such as might be seen in your bearings under heavy load.
To see how this all impacts oil performance, the High Temp High Shear (HTHS) viscosity of these oils is a good indicator. The HTHS viscosity is a measure of the oil's viscosity at 300F under heavy shear, as might be seen in your bearings. Higher is better.
Mobil 1 10w30 - 3.0
Mobil 1 5w30 - 3.1
AMSOIL Sig Series 5w30 - 3.2
AMSOIL Sig Series 10w30 - 3.2
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Mobil 1 High Mileage 5w30: 3.3
Mobil 1 High Mileage 10w30 - 3.5
AMSOIL ZROD 10w30 - 3.6
The top four comply with API SN limit of 800 ppm phosphorus. The Mobil 1 High Mileage 5w30 and 10w30 have 1000 ppm phosphorus, 1100 ppm zinc. The AMSOIL ZROD 10w30 has 1320 ppm phosphorus and 1440 ppm zinc. As can be seen, the oils that comply with current API SN specs have the lowest HTHS. Step up to oils that do not comply with the current API SN spec, the Mobil 1 High Mileage and the AMSOIL classic car ZROD and you can see a jump in HTHS.
:cheers: